Aqua­{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ3 N,N′,N′′}bis­(thio­cyanato-κN)nickel(II)

نویسندگان

  • Nura Suleiman Gwaram
  • Siti Munirah Saharin
  • Hamid Khaledi
  • Hapipah Mohd Ali
چکیده

In the title compound, [Ni(NCS)(2)(C(11)H(17)N(3))(H(2)O)], the Ni(II) ion is six-coordinated by the N,N',N"-tridentate Schiff base N atoms, two cis-positioned N-bound isothio-cyanate groups and one water mol-ecule. In the crystal, O-H⋯S hydrogen bonds link adjacent mol-ecules into infinite layers parallel to the ac plane. The layers are further connected into a three-dimensional network via C-H⋯π inter-actions. The -CH(2)-N(CH(3))(2) fragment is disordered over two sets of sites in a 0.556 (5):0.444 (5) ratio.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

{N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ4 N,N′,N′′,N′′′}bis­(thio­cyanato-κN)manganese(II)

The mol-ecule of the title compound, [Mn(NCS)(2)(C(16)H(18)N(4))], has crystallographic twofold rotation symmetry, with the Mn(II) atom lying on the rotation axis. The Mn(II) atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thio-cyanate ligands, forming a distorted octa-hedral geometry.

متن کامل

Aqua­{2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ3 N,N′,N′′}bis­(thio­cyanato-κN)nickel(II)

In the title compound, [Ni(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Ni(II) ion is six-coordinated by the N,N',N''-tridentate Schiff base, the N atoms of two thio-cyanate ligands and one water O atom in a distorted octa-hedral geometry. Intra-molecular C-H⋯N and C-H⋯O hydrogen bonds occur. In the crystal, O-H⋯S, O-H⋯O and C-H⋯S hydrogen bonds link adjacent mol-ecules into layers parallel to the ac ...

متن کامل

{N,N-Dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ3 N,N′,N′′}bis­(thio­cyanato-κN)copper(II)

The asymmetric unit of the title compound, [Cu(NCS)(2)(C(11)H(17)N(3))], consists of two crystallographically independent mol-ecules. In each mol-ecule, the Cu(II) ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N',N"-tridentate Schiff base and one N-bound thio-cyanate ligand. The second N-donor thio-cyanate group, located at the apic...

متن کامل

catena-Poly[[{N,N-dimethyl-N′-[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine-κ3 N,N′,N′′}(thio­cyanato-κN)cadmium]-μ-thio­cyanato-κ2 S:N]

In the title compound, [Cd(NCS)(2)(C(11)H(17)N(3))](n), the Cd(II) atom is octa-hedrally coordinated by the N,N',N''-tridentate Schiff base ligand and one terminal thio-cyanate N atom. Two trans-N:S-bridging thio-cyanates complete the N(5)S donor set around the Cd atom. In the crystal, adjacent Cd(II) ions are linked by the thio-cyanate N:S-bridges into polymeric chains along the c axis.

متن کامل

Bromido{N-methyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ3 N,N′,N′′}­(thio­cyanato-κN)­copper(II)

In the title mononuclear copper(II) compound, [CuBr(NCS)(C(10)H(15)N(3))], the Cu(II) atom is five-coordinated by three N atoms of the Schiff base ligand, the N atom of a thio-cyanate ligand and by one bromide ion forming a distorted square-pyramidal geometry. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯Br hydrogen bonds into chains propagating along [101].

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011